Abstract
A VAST number of compounds are known that exhibit structure transformations in response to changes in temperature, pressure and/or composition. One such example is the family of perovskites, La1-xSrxMnO33 for a limited range of compositions (x), they undergo a structural phase transition from an orthorhombic to a rhombohedral form with increasing temperature1, 2. These compounds are also ferromagnetic, a property that arises from coupling between the charge carriers and localized spin moments of the manganese ions3–7. Here we show that, through careful tuning of the composition, the local spin moments and the charge carriers can in turn be coupled strongly to changes in the structure. For x = 0.170, the crystal structure of the compound can be switched—reversibly or irreversibly, depending on the temperature—by application of an external magnetic field.
This is a preview of subscription content, access via your institution
Access options
Subscribe to this journal
Receive 51 print issues and online access
$199.00 per year
only $3.90 per issue
Buy this article
- Purchase on Springer Link
- Instant access to full article PDF
Prices may be subject to local taxes which are calculated during checkout
Similar content being viewed by others
References
Tokura, Y. et al. J. phys. Soc. Japan 63, 3931–3935 (1994).
Wold, A. & Arnott, R. J. J. Phys. Chem. Solids 9, 176–180 (1959).
Jonker, G. H. & Van Santen, J. H. Physica 16, 337–349 (1950).
Jonker, G. H. Physica 22, 707–722 (1956).
Zener, C. Phys. Rev. 82, 403–405 (1951).
Anderson, P. W. & Hasegawa, H. Phys. Rev. 100, 675–681 (1955).
de Gennes, P.-G. Phys. Rev. 118, 141–154 (1960).
Goodenough, J. B. Prog. Solid State Chem. 5, 145 (1971).
Kusters, R. M., Singleton, D. A., Mcgreevy, R. & Hayes, W. Physica B155, 362–365 (1989).
Chahara, K., Ohno, T., Kasai, M. & Kozono, Y. Appl. Phys. Lett. 63, 1990–1992 (1993).
von Helmont, R., Wecker, J., Holzapfel, B., Schultz, M. & Samwer, K. Phys. Rev. Lett. 71, 2331–2333 (1993).
Jin, S. et al. Science 264, 413–415 (1994).
Furukawa, N. J. phys. Soc. Japan 63, 3214–3217 (1994).
Goodenough, J. B. & Longon, J. M. Landolt-Bomstein Tabelllen Vol. III/4a (Springer, Berlin, 1970).
Torrance, J. B., Lacorre, P. & Nazzal, A. I. Phys. Rev. B45, 8209–8212 (1992).
Author information
Authors and Affiliations
Rights and permissions
About this article
Cite this article
Asamitsu, A., Moritomo, Y., Tomioka, Y. et al. A structural phase transition induced by an external magnetic field. Nature 373, 407–409 (1995). https://doi.org/10.1038/373407a0
Received:
Accepted:
Issue Date:
DOI: https://doi.org/10.1038/373407a0
This article is cited by
-
Effect of annealing temperature on the photocatalytic activity of La0.8Nd0.1Sr0.1MnO3 manganite for methyl orange degradation and study of its thermoelectric properties using DFT calculations
Journal of Materials Science: Materials in Electronics (2023)
-
Doping nanoarchitectonics through exchange of Ag+ with Na+ in La0.7Ca0.1Sr0.1X0.1MnO3 (X = Ag+ or Na+) manganite ceramics for enhancement and levelling tendency of magneto resistivity
Applied Physics A (2022)
-
Magnetically driven phonon instability enables the metal–insulator transition in h-FeS
Nature Physics (2020)
-
K dopant effect on \({\hbox {La}}_{0.7}{\hbox {K}}_{x} {\hbox {Ca}}_{0.3-x}{\hbox {MnO}}_{3}\) (\(x=0,\) 0.05, 0.1) perovskite compounds: the structural, magnetic and magnetocaloric properties
Journal of Materials Science: Materials in Electronics (2020)
-
Progress in multiferroic and magnetoelectric materials: applications, opportunities and challenges
Journal of Materials Science: Materials in Electronics (2020)
Comments
By submitting a comment you agree to abide by our Terms and Community Guidelines. If you find something abusive or that does not comply with our terms or guidelines please flag it as inappropriate.