Abstract
OPTICALLY nonlinear organic materials show considerable potential for applications in optical signal processing and telecommunications1,2. Most materials are based on the p-nitro-aniline template, in which the optical nonlinearities are intimately associated with quasi-one-dimensional charge transfer. But there are problems associated with this conventional approach, arising from the strongly dipolar nature of the molecules2. It has recently been recognized3–5 that two- and three-dimensional stereochemistry offers new possibilities for the design and synthesis of optically nonlinear molecules, in which charge transfer is multidirectional rather than dipolar in character; octupolar nonlinearities have now been demonstrated in several molecular systems5–7. Tri-substituted ruthenium complexes6 appear particularly attractive because intense, multidirectional metal-to-ligand charge transfer leads to a significant enhancement of the optical nonlinearity, as quantified by the quadratic hyperpolarizability, β. Here we show that the choice of ligand can further increase β to values in excess of 10-27e.s.u., comparable to the best dipolar optically nonlinear molecules.
This is a preview of subscription content, access via your institution
Access options
Subscribe to this journal
Receive 51 print issues and online access
$199.00 per year
only $3.90 per issue
Buy this article
- Purchase on Springer Link
- Instant access to full article PDF
Prices may be subject to local taxes which are calculated during checkout
Similar content being viewed by others
References
Chemla, D. S. & Zyss, J. (eds) Nonlinear Optical Properties of Organic Molecules and Crystals (Academic, Boston, 1987).
Zyss, J. (ed.) Molecular Nonlinear Optics: Materials, Physics and Devices (Academic, Boston, 1993).
Zyss, J. Nonlin. Opt. 1, 3–18 (1991).
Zyss, J. J. chem. Phys. 98, 6583–6599 (1993).
Zyss, J. & Ledoux, I. Chem. Rev. 94, 77–105 (1994).
Zyss, J., Dhenaut, C., Chau Van, T. & Ledoux, I. Chem. Phys. Lett. 206, 409–414 (1993).
Verbiest, T. et al. Opt. Lett. 18, 525 (1993).
Oudar, J-L. J. chem. Phys. 67, 446–457 (1977).
Terhune, R. W., Maker, P. D. & Savage, C. M. Phys. Rev. Lett. 14, 681–684 (1965).
Maker, P. D. Phys. Rev. A1, 923–951 (1970).
Cyvin, S. G., Rauch, J. E. & Decius, J. C. J. chem. Phys. 43, 4083–4095 (1965).
Joffre, M., Yaron, D., Silbey, R. J. & Zyss, J. J. chem. Phys 97, 5607–5615 (1992).
Barzoukas, M., Blanchard-Desce, M., Josse, D., Lehn, J-M. & Zyss, J. Chem. Phys. 133, 323–329 (1989).
Blanchard-Desce, M., Lehn, J-M., Barzoukas, M., Ledoux, I. & Zyss, J. Chem. Phys. 181, 281–289 (1994).
Rao, V. P., Jen, A. K. Y., Wong, K. Y. & Drost, K. J. J. chem. Soc., chem. Commun. 1118–1120 (1993).
Gilmour, S. et al. Chem. Mater. 6, 1603–1604 (1994).
Juris, A. et al. Coord. Chem. Rev. 84, 85–277 (1988).
Loucif-Saibi, R. et al. Chem. Phys. 167, 369–375 (1992).
Bourgault, M. et al. J. chem. Soc. chem. Commun. 1623–1624 (1993).
Nunzi, J-M., Charra, F., Fiorini, C. & Zyss, J. Chem. Phys. Lett. 219, 349–354 (1994).
Charra, F., Kajzar, F., Nunzi, J-M., Raimond, P. & Idiart, E. Opt. Lett. 18, 941–943 (1993).
Fiorini, C., Charra, F., Nunzi, J-M. & Zyss, J. in Proc. Eur. Conf. Laser and Electro-optics 33–34 (IEEE, Piscataway, 1994).
Juris, A., Campagna, S., Bidd, I., Lehn, J-M. & Ziessel, R. Inorg. Chem. 27, 4007–4011 (1988).
Kocian, O., Mortimer, R. J. & Beer, P. D. J. chem. Soc., Perkin Trans. I 3203–3205 (1990).
Kelly, J. M., O'Connell, C. M. & Vos, J. G. Inorg. Chim. Acta 64, L75–L76 (1982).
Sullivan, B. P., Salmon, D. J. & Meyer, T. J. Inorg. Chem. 17, 3334–3341 (1978).
Author information
Authors and Affiliations
Rights and permissions
About this article
Cite this article
Dhenaut, C., Ledoux, I., Samuel, I. et al. Chiral metal complexes with large octupolar optical nonlinearities. Nature 374, 339–342 (1995). https://doi.org/10.1038/374339a0
Received:
Accepted:
Issue Date:
DOI: https://doi.org/10.1038/374339a0
This article is cited by
-
First coordination polymer based on diterpenoids. Synthesis, structure, and magnetic properties
Russian Chemical Bulletin (2017)
-
Synthesis, spectral, theoretical calculations and optical properties performance of substituted-azobenzene dyes
Optical and Quantum Electronics (2016)
-
Three-way switching in a cyanide-bridged [CoFe] chain
Nature Chemistry (2012)
-
Lipase catalyse glycerolysis for kinetic resolution of racemates
Bioprocess and Biosystems Engineering (2007)
-
Synthesis, characterization and third-order nonlinear optical properties of ruthenium(II) complexes containing 2-(4-nitrophenyl)imidazo[4,5-f] [1,10]phenanthroline
Transition Metal Chemistry (2004)
Comments
By submitting a comment you agree to abide by our Terms and Community Guidelines. If you find something abusive or that does not comply with our terms or guidelines please flag it as inappropriate.
