Abstract
Magic-angle twisted bilayer graphene (MATBG) hosts a number of correlated states of matter that can be tuned by electrostatic doping1,2,3,4. Transport5,6 and scanning-probe7,8,9 experiments have shown evidence for band, correlated and Chern insulators along with superconductivity. This variety of in situ tunable states has allowed for the realization of tunable Josephson junctions10,11,12. However, although phase-coherent phenomena have been measured10,11,12, no control of the phase difference of the superconducting condensates has been demonstrated so far. Here we build on previous gate-defined junction realizations and form a superconducting quantum interference device13 (SQUID) in MATBG, where the superconducting phase difference is controlled through the magnetic field. We observe magneto-oscillations of the critical current, demonstrating long-range coherence of superconducting charge carriers with an effective charge of 2e. We tune to both asymmetric and symmetric SQUID configurations by electrostatically controlling the critical currents through the junctions. This tunability allows us to study the inductances in the device, finding values of up to 2 μH. Furthermore, we directly probe the current–phase relation of one of the junctions of the device. Our results show that complex devices in MATBG can be realized and used to reveal the properties of the material. We envision our findings, together with the established history of applications SQUIDs have14,15,16, will foster the development of a wide range of devices such as phase-slip junctions17 or high kinetic inductance detectors18.
This is a preview of subscription content, access via your institution
Access options
Access Nature and 54 other Nature Portfolio journals
Get Nature+, our best-value online-access subscription
$29.99 / 30 days
cancel any time
Subscribe to this journal
Receive 12 print issues and online access
$259.00 per year
only $21.58 per issue
Buy this article
- Purchase on Springer Link
- Instant access to full article PDF
Prices may be subject to local taxes which are calculated during checkout
Similar content being viewed by others
Data availability
The data that support the findings of this study are available online through the ETH Research Collection at https://doi.org/10.3929/ethz-b-000563127. This includes analysis and plotting scripts for Figs. 1–3, Extended Data Figs. 2–9 and Supplementary Information Figs. 1–3. It also includes raw microscopy files for Extended Data Fig. 1.
Code availability
The code used for plotting the figures is available online through the ETH Research Collection at https://doi.org/10.3929/ethz-b-000563127.
References
Cao, Y. et al. Unconventional superconductivity in magic-angle graphene superlattices. Nature 556, 43–50 (2018).
Cao, Y. et al. Correlated insulator behaviour at half-filling in magic-angle graphene superlattices. Nature 556, 80–84 (2018).
Lu, X. et al. Superconductors, orbital magnets and correlated states in magic-angle bilayer graphene. Nature 574, 653–657 (2019).
Li, G. et al. Observation of Van Hove singularities in twisted graphene layers. Nat. Phys. 6, 109–113 (2010).
Yankowitz, M. et al. Tuning superconductivity in twisted bilayer graphene. Science 363, 1059–1064 (2019).
Das, I. et al. Symmetry-broken Chern insulators and Rashba-like Landau-level crossings in magic-angle bilayer graphene. Nat. Phys. 17, 710–714 (2021).
Jiang, Y. et al. Charge order and broken rotational symmetry in magic-angle twisted bilayer graphene. Nature 573, 91–95 (2019).
Nuckolls, K. P. et al. Strongly correlated Chern insulators in magic-angle twisted bilayer graphene. Nature 588, 610–615 (2020).
Choi, Y. et al. Correlation-driven topological phases in magic-angle twisted bilayer graphene. Nature 589, 536–541 (2021).
de Vries, F. K. et al. Gate-defined Josephson junctions in magic-angle twisted bilayer graphene. Nat. Nanotechnol. 16, 760–763 (2021).
Rodan-Legrain, D. et al. Highly tunable junctions and non-local Josephson effect in magic-angle graphene tunnelling devices. Nat. Nanotechnol. 16, 769–775 (2021).
Diez-Merida, J. et al. Magnetic Josephson junctions and superconducting diodes in magic angle twisted bilayer graphene. Preprint at https://arxiv.org/abs/2110.01067 (2021).
Tinkham, M. Introduction to Superconductivity (Dover, 2004).
Palacios-Laloy, A. et al. Tunable resonators for quantum circuits. J. Low Temp. Phys. 151, 1034–1042 (2008).
Koch, J. et al. Charge-insensitive qubit design derived from the cooper pair box. Phys. Rev. A 76, 042319 (2007).
Orlando, T. P. et al. Superconducting persistent-current qubit. Phys. Rev. B 60, 15398–15413 (1999).
Mooij, J. E. & Nazarov, Y. V. Superconducting nanowires as quantum phase-slip junctions. Nat. Phys. 2, 169–172 (2006).
Day, P. K., LeDuc, H. G., Mazin, B. A., Vayonakis, A. & Zmuidzinas, J. A broadband superconducting detector suitable for use in large arrays. Nature 425, 817–821 (2003).
Clarke, J. & Braginski, A. I. The SQUID Handbook Vol. 2: Applications of SQUIDs and SQUID Systems (Wiley-VCH, 2006).
Little, W. A. et al. Observation of quantum periodicity in the transition temperature of a superconducting cylinder. Phys. Rev. Lett. 9, 9–12 (1962).
Kemppinen, A. et al. Suppression of the critical current of a balanced superconducting quantum interference device. Appl. Phys. Lett. 92, 052110 (2008).
Larsen, T. W. et al. Semiconductor-nanowire-based superconducting qubit. Phys. Rev. Lett. 115, 127001 (2015).
Wang, J. I.-J. et al. Coherent control of a hybrid superconducting circuit made with graphene-based van der Waals heterostructures. Nat. Nanotechnol. 14, 120–125 (2019).
Courtois, H., Meschke, M., Peltonen, J. T. & Pekola, J. P. Origin of hysteresis in a proximity josephson junction. Phys. Rev. Lett. 101, 067002 (2008).
Cardwell, D. & Ginley, D. Handbook of Superconducting Materials 1st edn (CRC Press, 2002).
Goswami, S. et al. Quantum interference in an interfacial superconductor. Nat. Nanotechnol. 11, 861–865 (2016).
Nichele, F. et al. Relating Andreev bound states and supercurrents in hybrid Josephson junctions. Phys. Rev. Lett. 124, 226801 (2020).
Tesche, C. D. & Clarke, J. dc SQUID: noise and optimization. J. Low Temp. Phys. 29, 301–331 (1977).
Beenakker, C. W. J. in Transport Phenomena in Mesoscopic Systems (Fukuyama, H. & Ando, T., eds) 235–253 (Springer, 1992).
Della Rocca, M. L. et al. Measurement of the current-phase relation of superconducting atomic contacts. Phys. Rev. Lett. 99, 127005 (2007).
Oh, M. et al. Evidence for unconventional superconductivity in twisted bilayer graphene. Nature 600, 240–245 (2021).
Kim, K. et al. Van der Waals heterostructures with high accuracy rotational alignment. Nano Lett. 16, 1989–1995 (2016).
Uri, A. et al. Mapping the twist-angle disorder and Landau levels in magic-angle graphene. Nature 581, 47–52 (2020).
Grover, F. W. Inductance Calculations: Working Formulas and Tables (Dover, 1962).
Acknowledgements
We thank P. Märki, L. Ginzburg, P. Tomić and the staff of the ETH cleanroom facility FIRST for technical support. We thank H. Pothier for helpful and detailed discussions on superconducting devices and O. Zilberberg, J. Cole and members of the quantum e-leaps consortium for comments on our data. We acknowledge financial support by the European Graphene Flagship, the ERC Synergy Grant Quantropy, the European Union’s Horizon 2020 research and innovation programme under grant agreement number 862660/QUANTUM E LEAPS and NCCR QSIT (Swiss National Science Foundation). K.W. and T.T. acknowledge support from the Elemental Strategy Initiative conducted by the MEXT, Japan (grant number JPMXP0112101001) and JSPS KAKENHI (grant numbers 19H05790, 20H00354 and 21H05233). E.P. acknowledges support of a fellowship from ‘la Caixa’ Foundation (ID 100010434) under fellowship code LCF/BQ/EU19/11710062.
Author information
Authors and Affiliations
Contributions
E.P. fabricated the device. T.T. and K.W. supplied the hBN crystals. E.P. and F.K.d.V. performed the measurements and analysis of the data. E.P., F.K.d.V., S.I., G.Z. and P.R. discussed the data. F.K.d.V., T.I. and K.E. supervised the project. E.P. and F.K.d.V. wrote the manuscript with comments from all authors.
Corresponding authors
Ethics declarations
Competing interests
The authors declare no competing interests.
Peer review
Peer review information
Nature Nanotechnology thanks the anonymous reviewers for their contribution to the peer review of this work.
Additional information
Publisher’s note Springer Nature remains neutral with regard to jurisdictional claims in published maps and institutional affiliations.
Extended data
Extended Data Fig. 1 Device fabrication: Capture of the design file and optical images taken during the fabrication process.
a Optical image of the device after etching and evaporation of the gold contacts. The scale bar corresponds to a length of 1μm. b Optical image of the device after mesa etching. c Optical image of the device after the deposition of a layer of aluminium oxide and definition and evaporation of top gates. d Capture of the design file of the device. Contacts are depicted in yellow, etched areas in pink and top gates in white.
Extended Data Fig. 2 Density maps and angle extraction.
a Differential resistance maps across the device as a function of electron density in regions biased by only the back gate (global) or both back and top gates. The data in the left panel corresponds to VG1 being swept and gate 2 being fixed at VG2 = 10V. In the centre panel VG2 is swept while gate 1 is kept constant at VG1 = 10V. In the right panel both top gates are swept together. Densities are computed from the model described in the Methods section. Black dashed lines indicate the values at which we consider the flat bands to be fully filled. These values are then used to extract the twist angle of the device. b Extended range trace of the resistance as a function of the global density induced by the back gate, with each local top gate set to zero.
Extended Data Fig. 3 Resistance of the device as a function of density.
VG1 and VG2 are kept at zero volts. We plot the derivative of the measured voltage drop as a function of the current bias, which corresponds to the differential resistance R = dV/dIdc across the device. The red dashed line indicates the ’optimal density’ nopt = − 1.27 × 1012cm−2 at which we set the back gate when wanting to maximize the critical current through the device. The upper axis indicates the filling factors corresponding to the electron densities.
Extended Data Fig. 4 Differential resistance across each arm of the loop as a function of local densities.
The back gate is tuned to its optimal point nopt = − 1.27 × 1012cm−2. We step the local top gate of each arm and sweep the current bias. For a, the voltage bias of gate G2 is fixed at VG2 = 10V, to prevent any supercurrent from going through it, while we step G1. For b the configuration is the opposite, we have VG1 = 10V while we step VG2. The dashed lines correspond to the voltage of each top gate at the asymmetric (orange) and symmetric (red) regime measurements shown in Fig. 1d,e.
Extended Data Fig. 5 Critical field at each arm of the device.
The voltage of the back gate is set to the optimal point for every figure. a Differential resistance as a function of current bias and magnetic field when VG1 = 10V, preventing any supercurrent from flowing through arm 1 and VG2 = -0.5V maximizes the critical current of arm 2. We thus observe the resistance across arm 2 of the device as a function of current and magnetic field. b Same measurement as in a, this time with VG2 = 10V and VG1 = -0.37V.
Extended Data Fig. 6 Hysteresis and discontinuities in the critical current as a function of magnetic field.
Each line represents a CPR trace taken at the most asymmetric regime of the device. The magnetic field is swept from negative to positive in a small range, then the direction is reversed and the range increased. This procedure is repeated several times to obtain the data shown in the figure. Switches in the CPR traces and hysteresis appear as the range of the magnetic field sweep increases. We can not rule out a ferromagnetic part of the cryostat or the superconducting magnet to be at the origin of this phenomenon. Therefore, we do not highlight it in the main text.
Extended Data Fig. 7 Presence or absence of oscillations depending on the current sweep direction.
The device is in the most asymmetric configuration. The left panel of the figure is a zoom in of Fig. 1. We measure the voltage drop across the device as a function of magnetic field and current. We observe oscillations due to superconducting interference in the superconducting lobe or the switching current but no oscillations for the retrapping current. The current bias is swept from negative to positive values in the left panel and from positive to negative in the right panel.
Extended Data Fig. 8 Voltage drop over the device when biased above the critical current in the symmetric regime.
The curves show the voltage drop across the device as a function of magnetic field with a different current bias for each curve. Black dotted lines are guides to the eye plotted using equation (S1) fixing Ic at 2.25 nA.
Extended Data Fig. 9 Resistance across the device as a function of density and temperature.
The black dotted line highlights the superconducting lobe. The line is taken where the resistance is 50% of the normal state resistance.
Supplementary information
Supplementary Information
Supplementary Discussion and Figs. 1–3.
Rights and permissions
Springer Nature or its licensor holds exclusive rights to this article under a publishing agreement with the author(s) or other rightsholder(s); author self-archiving of the accepted manuscript version of this article is solely governed by the terms of such publishing agreement and applicable law.
About this article
Cite this article
Portolés, E., Iwakiri, S., Zheng, G. et al. A tunable monolithic SQUID in twisted bilayer graphene. Nat. Nanotechnol. 17, 1159–1164 (2022). https://doi.org/10.1038/s41565-022-01222-0
Received:
Accepted:
Published:
Issue Date:
DOI: https://doi.org/10.1038/s41565-022-01222-0
This article is cited by
-
Tunable quantum interferometer for correlated moiré electrons
Nature Communications (2024)
-
The Roadmap of 2D Materials and Devices Toward Chips
Nano-Micro Letters (2024)
-
Electrical switching of a bistable moiré superconductor
Nature Nanotechnology (2023)