Issue 2, 2000
From the journal:

Journal of the Chemical Society, Dalton Transactions

1-D mixed stack of coordinated and uncoordinated radicals in MnII(NITpPy)4[N(CN)2]2 (NITpPy = nitronyl nitroxide radical)

Iwayan Dasna,a   Stéphane Golhen,a   Lahcène Ouahab,*a   Octavio Peña,a   Joseph Guillevica  and  Mohammed Fettouhib  

* Corresponding authors

a Laboratoire de Chimie du Solide et Inorganique Moléculaire, UMR 6511, Université de Rennes 1, Campus Beaulieu 35042, Rennes cedex, France

b Chemistry Department, King Fahd University of Petroleum and Minerals, P.O. Box 5048, Dahran, Saudi Arabia

Abstract

The synthesis, X-ray crystal structures and magnetic properties of the 1-D polymeric coordination compound MnII(NITpPy)4[N(CN)2]2 (NITpPy = 2-(4-pyridyl)-4,4,5,5-tetramethylimidazoline-1-oxyl 3-oxide) are reported. In the crystal structure the [MnII(NITpPy)2]2+ units are linked by N(CN)2− μ-bridging ligands to form one dimensional polymeric columns. In the columns, the coordinated radicals alternate with uncoordinated ones. The magnetic properties obey a Curie–Weiss law with weak antiferromagnetic interactions.

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Article information

DOI
https://doi.org/10.1039/A908891A
Article type
Paper
Submitted
08 Nov 1999
Accepted
26 Nov 1999
First published
07 Jan 2000

J. Chem. Soc., Dalton Trans., 2000, 129-132

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1-D mixed stack of coordinated and uncoordinated radicals in MnII(NITpPy)4[N(CN)2]2 (NITpPy = nitronyl nitroxide radical)

I. Dasna, S. Golhen, L. Ouahab, O. Peña, J. Guillevic and M. Fettouhi, J. Chem. Soc., Dalton Trans., 2000, 129 DOI: 10.1039/A908891A

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