Issue 5, 2000
From the journal:

Chemical Communications

Enhanced regioselectivity of rhodium-catalysed alkenehydroboration in supercritical carbon dioxide

Charles A. G. Carter,a   R. Thomas Baker,*a   Steven P. Nolanb  and  William Tumas*a  

* Corresponding authors

a Los Alamos Catalysis Initiative, Chemical Science and Technology Division, Los Alamos National Laboratory, MS J514, Los Alamos, NM, USA.
E-mail: weg@lanl.gov; tumas@lanl.gov

b Department of Chemistry, University of New Orleans, New Orleans, LA, USA

Abstract

Catalysed alkene hydroboration proceeds in supercritical CO2 with several rhodium(I) complexes using tunable fluorinated ligands and shows higher regioselectivity relative to tetrahydrofuran or perfluoromethylcyclohexane.

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Article information

DOI
https://doi.org/10.1039/A909636A
Article type
Communication
Submitted
02 Dec 1999
Accepted
26 Jan 2000
First published
21 Feb 2000

Chem. Commun., 2000, 347-348

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Enhanced regioselectivity of rhodium-catalysed alkene hydroboration in supercritical carbon dioxide

C. A. G. Carter, R. T. Baker, S. P. Nolan and W. Tumas, Chem. Commun., 2000, 347 DOI: 10.1039/A909636A

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