Ion-selective electrodes for divalent metal ions (Cu2+, Pb2+, Cd2+, Hg2+) have been prepared by covering ionic conductors such as Ag2S, Ag3SBr or Ag3SI with a thin metal sulphide layer. The metal sulphide layer was treated by heating under a partial pressure of sulphur. The observed standard potential is a good criterion for judging electrode performance.
R. E. van de Leest, Analyst, 1977, 102, 509 DOI: 10.1039/AN9770200509
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