A variety of aromatic substrates were treated with 2-acetoxy-D-glucal in the presence of HF–pyridine to give 1-arylhex-3-enopyranosiduloses in high yield and in high α-selectivity.
HF–pyridine promoted Friedel–Crafts type arylation of 2-acetoxy-D-glucal. Stereoselective synthesis of 1-arylhex-3-enopyranosiduloses
M. Hayashi, S. Nakayama and H. Kawabata, Chem. Commun., 2000, 1329 DOI: 10.1039/B003302M
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