The complexation of the pentadentate ligand bis[1,1-di(2-pyridyl)ethyl]amine (BDPEA), by cobalt(II) salts leads to novel Co(II)/Co(III) mixed-valence complexes: the secondary amine of the starting BDPEA is deprotonated, leading to a dinucleating bridging amido ligand.
C. Hemmert, H. Gornitzka and B. Meunier, New J. Chem., 2000, 24, 949 DOI: 10.1039/B007907N
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