Issue 2, 2002

Abstract

We report the experimental measurements for etch rates of the +z and −z faces of single crystal lithium niobate immersed in HF and HNO3 acid mixtures of varying ratios. We find that pure HF produces an etch rate that is a factor of 2 higher than the rate obtained for the more frequently used mixture of HF/HNO3 in a 1∶2 ratio. We further observe that the quality of etching is improved for either pure HF or HF/HNO3 in a 1∶4 ratio, again by comparison with use of a 1∶2 ratio. These results lead to a discussion of the etch chemistry involved, and an explanation for the observed high degree of differential etching between the +z and −z crystal faces.

Graphical abstract: Differential etch rates in z-cut LiNbO3 for variable HF/HNO3 concentrations

Article information

Article type
Paper
Submitted
16 Jul 2001
Accepted
15 Nov 2001
First published
29 Nov 2001

J. Mater. Chem., 2002,12, 295-298

Differential etch rates in z-cut LiNbO3 for variable HF/HNO3 concentrations

C. L. Sones, S. Mailis, W. S. Brocklesby, R. W. Eason and J. R. Owen, J. Mater. Chem., 2002, 12, 295 DOI: 10.1039/B106279B

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