Issue 3, 2002
From the journal:

Chemical Communications

A new and short method for the synthesis of 2,4-methanoproline

Thomas Rammelooa  and  Christian V. Stevens*a  

* Corresponding authors

a Department of Organic Chemistry, Faculty of Agricultural and Applied Biological Sciences, Ghent University, Coupure links 653, Gent, Belgium
E-mail: Chris.Stevens@rug.ac.be
Fax: +32-9-264 62 43
Tel: +32-9-264 59 57

Abstract

2,4-Methanoproline, a supposed non-proteinogenic anti-feedant, was synthesised in 5 steps starting from allyl benzyl ether 3 in 10% overall yield with an intramolecular nucleophilic substitution as the key step for the formation of the bicyclic skeleton.

Graphical abstract: A new and short method for the synthesis of 2,4-methanoproline

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Article information

DOI
https://doi.org/10.1039/B110765H
Article type
Communication
Submitted
26 Nov 2001
Accepted
11 Dec 2001
First published
16 Jan 2002

Chem. Commun., 2002, 250-251

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A new and short method for the synthesis of 2,4-methanoproline

T. Rammeloo and C. V. Stevens, Chem. Commun., 2002, 250 DOI: 10.1039/B110765H

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