Issue 15, 2002
From the journal:

Chemical Communications

Silazanes/catalytic bases: mild, powerful and chemoselective agents for the preparation of enolsilyl ethers from ketones and aldehydes

Yoo Tanabe,*a   Tomonori Misaki,a   Minoru Kurihara,a   Akira Iidaa  and  Yoshinori Nishiia  

* Corresponding authors

a Department of Chemistry, School of Science and Technology, Kwansei Gakuin University, 2-1 Gakuen, Sanda, Hyogo 669-1337, Japan

Abstract

We have developed an efficient method for the preparation of enol silyl ethers using novel agents, silazanes together with NaH or DBU catalyst, wherein TMS and TBDMS groups were smoothly and chemoselectively introduced into ketones and aldehydes under mild conditions.

Graphical abstract: Silazanes/catalytic bases: mild, powerful and chemoselective agents for the preparation of enol silyl ethers from ketones and aldehydes

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Article information

DOI
https://doi.org/10.1039/B203783C
Article type
Communication
Submitted
18 Apr 2002
Accepted
05 Jun 2002
First published
28 Jun 2002

Chem. Commun., 2002, 1628-1629

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Silazanes/catalytic bases: mild, powerful and chemoselective agents for the preparation of enol silyl ethers from ketones and aldehydes

Y. Tanabe, T. Misaki, M. Kurihara, A. Iida and Y. Nishii, Chem. Commun., 2002, 1628 DOI: 10.1039/B203783C

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