Issue 18, 2002
From the journal:

Physical Chemistry Chemical Physics

Preferential solvation in mixed solvents.

Part 11.† Eight additional completely miscible aqueous co-solvent binary mixtures and the relationship between the volume-corrected preferential solvation parameters and the structures of the co-solvents

Yizhak Marcusa  

a Department of Inorganic and Analytical Chemistry, The Hebrew University of Jerusalem, Jerusalem, Israel
E-mail: ymarcus@vms.huji.ac.il

Abstract

The Kirkwood–Buff integrals and the volume-corrected preferential solvation parameters for the first solvation shell of the completely miscible aqueous binary mixtures of 1,3-oxolane, γ-butyrolactone, diethylamine, 1,2-diaminoethane, pyrrolidine, morpholine, N-methylacetamide and N,N,N′,N′-tetramethylurea were calculated from thermodynamic data at the temperatures for which these data were available. The preferential solvation parameters of these and 33 additional mixtures for which they have been published are related to the structures of the co-solvents.

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Article information

DOI
https://doi.org/10.1039/B205180J
Article type
Paper
Submitted
29 May 2002
Accepted
23 Jul 2002
First published
21 Aug 2002

Phys. Chem. Chem. Phys., 2002,4, 4462-4471

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Preferential solvation in mixed solvents.

Y. Marcus, Phys. Chem. Chem. Phys., 2002, 4, 4462 DOI: 10.1039/B205180J

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