Issue 6, 2003
From the journal:

Physical Chemistry Chemical Physics

Standard Gibbs energies of transfer of halogenate and pseudohalogenate ions, halogen substituted acetates, and cycloalkyl carboxylate anions at the water|nitrobenzene interface

Rubin Gulaboski,a   Kai Riedla  and  Fritz Scholz*a  

* Corresponding authors

a Ernst-Moritz-Arndt-Universität Greifswald, Institut für Chemie und Biochemie, Soldmannstraße 23, D-17489 Greifswald, Germany
E-mail: fscholz@uni-greifswald.de
Fax: +49 (0)3834 86 4451

Abstract

The previously introduced three-phase electrode technique was used to determine the Gibbs energies of transfer of ClO3−, BrO3−, IO3−, IO4−, OCN−, SeCN−, CN−, N3−, halogen substituted acetate anions Z3−nCHnCOO− (Z = F,Cl,Br,I), and cycloalkyl carboxylate anions ((CH2)nCOO−, n = 3,…,7) at the water|nitrobenzene interface. Whereas the data for the small inorganic ions can easily be understood in terms of ion-dipole interactions, the data of the organic ions need consideration of charge delocalisation and its effect on the enthalpy and entropy of solvation.

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Article information

DOI
https://doi.org/10.1039/B210356G
Article type
Paper
Submitted
24 Oct 2002
Accepted
27 Jan 2003
First published
07 Feb 2003

Phys. Chem. Chem. Phys., 2003,5, 1284-1289

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Standard Gibbs energies of transfer of halogenate and pseudohalogenate ions, halogen substituted acetates, and cycloalkyl carboxylate anions at the water|nitrobenzene interface

R. Gulaboski, K. Riedl and F. Scholz, Phys. Chem. Chem. Phys., 2003, 5, 1284 DOI: 10.1039/B210356G

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