Issue 4, 2003
From the journal:

Dalton Transactions

A two-dimensional framework of novel vanadium clusters bridged by [Ni(en)2]2+: K{V12IVV6VO42Cl[Ni(en)2]3}·8H2O

Cheng-Ling Pan,a   Ji-Qing Xu,*a   Guang-Hua Li,a   Xiao-Bing Cui,a   Ling Yeb  and  Guang-Di Yangb  

* Corresponding authors

a College of Chemistry, State Key Laboratory of Inorganic Synthesis and Preparative Chemistry, Jilin University, Changchun 130023, P. R. China
E-mail: xjq@mail.jlu.edu.cn

b Key Lab of Supramolecular Structure and Spectroscopy, Jilin University, P. R. China

Abstract

The hydrothermal reaction of V2O5, H2C2O4·2H2O, en, KOH and NiCl2·6H2O gives a new two-dimensional open-framework solid; the extended structure consists of a two-dimensional network formed by the interconnection of each [V18O42Cl] cage to four other neighboring units via six [Ni(en)2]2+ bridging groups.

Graphical abstract: A two-dimensional framework of novel vanadium clusters bridged by [Ni(en)2]2+: K{V12IVV6VO42Cl[Ni(en)2]3}·8H2O

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Article information

DOI
https://doi.org/10.1039/B211530C
Article type
Communication
Submitted
20 Nov 2002
Accepted
08 Jan 2003
First published
16 Jan 2003

Dalton Trans., 2003, 517-518

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A two-dimensional framework of novel vanadium clusters bridged by [Ni(en)2]2+: K{V12IVV6VO42Cl[Ni(en)2]3}·8H2O

C. Pan, J. Xu, G. Li, X. Cui, L. Ye and G. Yang, Dalton Trans., 2003, 517 DOI: 10.1039/B211530C

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