Issue 5, 2003
From the journal:

New Journal of Chemistry

Structural transformation mediated by o-, m-, and p-phthalates from two to three dimensions for manganese/phthalate/4,4′-bpy complexes (4,4′-bpy = 4,4′-bipyridine)

Chengbing Ma,ad   Changneng Chen,a   Qiutian Liu,*a   Daizheng Liao,b   Licun Lib  and  Licheng Sunc  

* Corresponding authors

a State Key Laboratory of Structural Chemistry, Fujian Institute of Research on the Structure of Matter, Chinese Academy of Sciences, Fuzhou, Fujian, China
E-mail: lqt@ms.fjirsm.ac.cn

b Department of Chemistry, Nankai University, Tainjin, China

c State Key Laboratory of Fine Chemicals, Dalian University of Technology, Dalian, China

d Graduate School of the Chinese Academy of Sciences, Beijing, China

Abstract

Three isomers of o-, m-, and p-phthalate are used to link together Mn centres, resulting in [Mn(phth)(H2O)x]n moieties (phth = phthalate dianion) with single-chain, double-chain and sheet structures, respectively, which predetermine the extended structures derived from the crosslinkage of 4,4′-bipyridine, and show the influence of isomerism of the phthalate on topological changes of the final polymers from two dimensional (2D) single-layer, double-layer to 3D network architectures. These structural changes in topology are correlated with the differences in the magnetic and optical properties of the polymers.

Graphical abstract: Structural transformation mediated by o-, m-, and p-phthalates from two to three dimensions for manganese/phthalate/4,4′-bpy complexes (4,4′-bpy = 4,4′-bipyridine)

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Article information

DOI
https://doi.org/10.1039/B301076G
Article type
Paper
Submitted
27 Jan 2003
Accepted
13 Mar 2003
First published
11 Apr 2003

New J. Chem., 2003,27, 890-894

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Structural transformation mediated by o-, m-, and p-phthalates from two to three dimensions for manganese/phthalate/4,4′-bpy complexes (4,4′-bpy = 4,4′-bipyridine)

C. Ma, C. Chen, Q. Liu, D. Liao, L. Li and L. Sun, New J. Chem., 2003, 27, 890 DOI: 10.1039/B301076G

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