Issue 11, 2003
From the journal:

Chemical Communications

A novel left-handed double helicate constructed from l-tartrate bridged molybdenum(vi) and gadolinium(iii) atoms†

Chuan-De Wu,a   Can-Zhong Lu,*a   Xiang Lin,a   Ding-Ming Wu,a   Shao-Fang Lu,a   Hong-Hui Zhuanga  and  Jin-Shun Huanga  

* Corresponding authors

a The State Key Laboratory of Structural Chemistry, Fujian Institute of Research on the Structure of Matter, The Chinese Academy of Sciences, Fuzhou, Fujian 350002, P. R. China
E-mail: czlu@ms.fjirsm.ac.cn

Abstract

The one-dimensional double helicate, [NH4][Mo2O4Gd(H2O)6(L-C4H2O6)2]ยท4H2O (1), which was synthesized by the reaction of GdCl3, L-tartaric acid and ammonium molybdate in acidified water solution, is built up by two heft-handed single-helical chains, linked up further by eight-coordinated GdIII pieces in an enantiopure left-handed double helical configuration, of which each helix is formed by L-tartrate bridged six-coordinated MoVI atoms.

Graphical abstract: A novel left-handed double helicate constructed from l-tartrate bridged molybdenum(vi) and gadolinium(iii) atoms

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Article information

DOI
https://doi.org/10.1039/B301542D
Article type
Communication
Submitted
11 Feb 2003
Accepted
07 Apr 2003
First published
02 May 2003

Chem. Commun., 2003, 1284-1285

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A novel left-handed double helicate constructed from L-tartrate bridged molybdenum(VI) and gadolinium(III) atoms

C. Wu, C. Lu, X. Lin, D. Wu, S. Lu, H. Zhuang and J. Huang, Chem. Commun., 2003, 1284 DOI: 10.1039/B301542D

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