Issue 5, 2004

A host–guest complex between a metal–organic cyclotriveratrylene analog and a polyoxometalate: [Cu6(4,7-phenanthroline)8(MeCN)4]2PM12O40 (M = Mo or W)

Abstract

The synthesis and crystal structure of Cu6(4,7-phenanthroline)8(MeCN)46+ a novel Cu(I)-molecular hexamer is described in which the metal cations and phenanthroline molecules self-assemble into a dimer of shallow triangular-shaped bowls, within which are located large spherical polyoxometalate anions PM12O403− (M = Mo or W).

Graphical abstract: A host–guest complex between a metal–organic cyclotriveratrylene analog and a polyoxometalate: [Cu6(4,7-phenanthroline)8(MeCN)4]2PM12O40 (M = Mo or W)

Supplementary files

Article information

Article type
Communication
Submitted
06 Aug 2003
Accepted
15 Dec 2003
First published
27 Jan 2004

Chem. Commun., 2004, 492-493

A host–guest complex between a metal–organic cyclotriveratrylene analog and a polyoxometalate: [Cu6(4,7-phenanthroline)8(MeCN)4]2PM12O40 (M = Mo or W)

J. M. Knaust, C. Inman and S. W. Keller, Chem. Commun., 2004, 492 DOI: 10.1039/B309255K

To request permission to reproduce material from this article, please go to the Copyright Clearance Center request page.

If you are an author contributing to an RSC publication, you do not need to request permission provided correct acknowledgement is given.

If you are the author of this article, you do not need to request permission to reproduce figures and diagrams provided correct acknowledgement is given. If you want to reproduce the whole article in a third-party publication (excluding your thesis/dissertation for which permission is not required) please go to the Copyright Clearance Center request page.

Read more about how to correctly acknowledge RSC content.

Social activity

Spotlight

Advertisements