Issue 8, 2004

Critical viscosity near the liquid–liquid phase transition in the solution of the ionic liquid1-methyl-3-hexylimidazolium tetrafluoroborate in 1-pentanol

Abstract

In this work, we report measurements of viscosity and density near the liquid–liquid phase transition of the binary solution of the room temperature ionic liquid (RTIL) 1-methyl-3-hexylimidazolium tetrafluoroborate (C6mim+BF4) in 1-pentanol. The density and the shear viscosity have been determined as function of the temperature and of the concentration. The critical point is located at the temperature Tc = 314.91 K and the mass fraction wc = 0.31034 of the salt. For the critical concentration, the viscosity measurements yield an enhancement as expected for Ising criticality with a crossover to regular behaviour. The regular background is obtained by interpolation from the measurements at non-critical concentrations. The critical enhancement is well described by the mode-coupling crossover function of Bhattacharjee et al. (Phys. Rev. A, 1981, 24, 1469) .The closed form result of the limiting case qD/qc → 0 matches the data almost perfectly.

Article information

Article type
Paper
Submitted
02 Dec 2003
Accepted
05 Feb 2004
First published
04 Mar 2004

Phys. Chem. Chem. Phys., 2004,6, 1750-1757

Critical viscosity near the liquid–liquid phase transition in the solution of the ionic liquid 1-methyl-3-hexylimidazolium tetrafluoroborate in 1-pentanol

M. Wagner, O. Stanga and W. Schröer, Phys. Chem. Chem. Phys., 2004, 6, 1750 DOI: 10.1039/B315616H

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