Issue 11, 2004
From the journal:

Dalton Transactions

Synthesis of photo-luminescent Zn(ii) Schiff base complexes and its derivative containing Pd(ii) moiety

Ku-Hsien Chang,a   Chiung-Cheng Huang,a   Yi-Hung Liu,a   Ya-Hui Hu,a   Pi-Tai Choua  and  Ying-Chih Lin*a  

* Corresponding authors

a Department of Chemistry, National Taiwan University, Taipei, Taiwan
E-mail: yclin@ntu.edu.tw
Fax: (886)-2-23636359

Abstract

An efficient method was developed for the preparation of a series of zinc Schiff base complexes. Introduction of a pyridyl group as a bridging unit as well as incorporation of ethynyl and electron-donating groups into the salicylidene moiety of these complexes moderately enhances the photoluminescence intensity and quantum yield. Electron-rich palladium groups possibly influence the photophysical character through the bridging C[triple bond, length as m-dash]C bond. The crystal structure of the pyridine adduct of a salen Zn complex is determined by X-ray diffraction analysis.

Graphical abstract: Synthesis of photo-luminescent Zn(ii) Schiff base complexes and its derivative containing Pd(ii) moiety

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Article information

DOI
https://doi.org/10.1039/B316281H
Article type
Paper
Submitted
12 Dec 2003
Accepted
02 Apr 2004
First published
26 Apr 2004

Dalton Trans., 2004, 1731-1738

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Synthesis of photo-luminescent Zn(II) Schiff base complexes and its derivative containing Pd(II) moiety

K. Chang, C. Huang, Y. Liu, Y. Hu, P. Chou and Y. Lin, Dalton Trans., 2004, 1731 DOI: 10.1039/B316281H

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