Issue 58, 2004

2,7-di-p-Chlorobenzoylnaphtho[2′3′-4 : 5]thiepin: a conformationally flexible new host molecule showing solvatochromic effects

Abstract

The title host molecule exhibits remarkable conformational flexibility in its crystalline inclusion compounds. The alteration in molecular conformation, between the red dioxane and yellow benzene clathrates, corresponds to a dramatic change in the boat conformation of the seven-membered thiepin ring and reorientation of the side chains.

Graphical abstract: 2,7-di-p-Chlorobenzoylnaphtho[2′3′-4 : 5]thiepin: a conformationally flexible new host molecule showing solvatochromic effects

Supplementary files

Additions and corrections

Article information

Article type
Communication
Submitted
16 Sep 2004
Accepted
21 Sep 2004
First published
04 Oct 2004

CrystEngComm, 2004,6, 326-327

2,7-di-p-Chlorobenzoylnaphtho[2′3′-4 : 5]thiepin: a conformationally flexible new host molecule showing solvatochromic effects

L. Ballie, L. J. Farrugia, D. D. MacNicol and R. MacSween, CrystEngComm, 2004, 6, 326 DOI: 10.1039/B414315A

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