Issue 38, 2005
From the journal:

CrystEngComm

Bipyridine conformations control the solid-state supramolecular chemistry of zinc(ii) phthalocyanine with bipyridines

Qingdao Zeng,*a   Dongxia Wu,a   Chen Wang,*b   Jun Lu,a   Baocheng Ma,a   Chunying Shu,a   Hongwei Ma,a   Yan Lia  and  Chunli Bai*ab  

* Corresponding authors

a Center for Molecular Science, Institute of Chemistry, The Chinese Academy of Sciences, Beijing, P. R. China
E-mail: stmzqd@iccas.ac.cn and clbai@iccas.ac.cn

b National Center for Nanoscience and Technology, Beijing, P. R. China
E-mail: wangch@iccas.ac.cn.

Abstract

Two H-shaped supramolecular complexes (C32H16N8Zn)2·(C12H12N2)·0.96H2O (1), (C32H16N8Zn)2·(C12H10N2)·(DMF)2 (2), and one T-shaped supramolecular complex C32H16N8Zn·C13H14N2 (3) have been prepared from zinc(II) phthalocyanine with 1,2-bis(4-pyridyl)ethane (bipy-eta), 1,2-di(4-pyridyl)ethylene (dipy-ete) or 1,3-di(4-pyridyl)propane (dipy-pra), respectively, and characterized by single-crystal X-ray diffraction, electronic absorption spectra and fluorescence spectra; the conformation of the bipyridines plays an important role in the assembly processes.

Graphical abstract: Bipyridine conformations control the solid-state supramolecular chemistry of zinc(ii) phthalocyanine with bipyridines

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Article information

DOI
https://doi.org/10.1039/B502587G
Article type
Communication
Submitted
21 Feb 2005
Accepted
21 Mar 2005
First published
24 Mar 2005

CrystEngComm, 2005,7, 243-248

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Bipyridine conformations control the solid-state supramolecular chemistry of zinc(II) phthalocyanine with bipyridines

Q. Zeng, D. Wu, C. Wang, J. Lu, B. Ma, C. Shu, H. Ma, Y. Li and C. Bai, CrystEngComm, 2005, 7, 243 DOI: 10.1039/B502587G

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