Issue 8, 2005
From the journal:

Green Chemistry

PS–BQ: an efficient polymer-supported cocatalyst for the Wacker reaction in supercritical carbon dioxide

Zhao-Yang Wang,ab   Huan-Feng Jiang,*a   Chao-Rong Qi,a   Yu-Gang Wang,a   Yao-Sen Donga  and  Hai-Ling Liua  

* Corresponding authors

a Center of Green Chemistry, College of Chemistry, South China University of Technology, Guangzhou 510640, P. R. China
E-mail: jianghf@scut.edu.cn

b Department of Chemistry, School of Chemistry and Environment, South China Normal University, Guangzhou 510631, P. R. China
E-mail: wangwangzhaoyang@tom.com

Abstract

Using polystyrene-supported benzoquinone (PS–BQ) as cocatalyst with palladium chloride, the acetalization of terminal olefins with electron-withdrawing groups, i.e., acrylate esters, acrylonitrile, methyl vinyl ketone and acrolein, was carried out smoothly in supercritical carbon dioxide under oxygen atmosphere.

Graphical abstract: PS–BQ: an efficient polymer-supported cocatalyst for the Wacker reaction in supercritical carbon dioxide

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Article information

DOI
https://doi.org/10.1039/B505515F
Article type
Paper
Submitted
19 Apr 2005
Accepted
02 Jun 2005
First published
29 Jun 2005

Green Chem., 2005,7, 582-585

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PS–BQ: an efficient polymer-supported cocatalyst for the Wacker reaction in supercritical carbon dioxide

Z. Wang, H. Jiang, C. Qi, Y. Wang, Y. Dong and H. Liu, Green Chem., 2005, 7, 582 DOI: 10.1039/B505515F

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