Coordination chemistry of the hexavacant tungstophosphate [H2P2W12O48]12−: synthesis and characterization of iron(III) complexes derived from the unprecedented {P2W14O54} fragment

Béatrice Godin; Jacqueline Vaissermann; Patrick Herson; Laurent Ruhlmann; Michel Verdaguer; Pierre Gouzerh

doi:10.1039/B510434C

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Coordination chemistry of the hexavacant tungstophosphate [H₂P₂W₁₂O₄₈]¹²⁻: synthesis and characterization of iron(iii) complexes derived from the unprecedented {P₂W₁₄O₅₄} fragment†

Béatrice Godin,^a Jacqueline Vaissermann,^a Patrick Herson,^a Laurent Ruhlmann,^a Michel Verdaguer^a and Pierre Gouzerh*^a

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* Corresponding authors

^a Laboratoire de Chimie Inorganique et Matériaux Moléculaires, UMR CNRS 7071, Institut de Chimie Moléculaire FR 2769, Université Pierre et Marie Curie, 4 Place Jussieu, 75252 Paris Cedex 05, France
E-mail: pg@ccr.jussieu.fr
Fax: 33 1 44 27 38 41
Tel: 33 1 44 27 55 53

Abstract

Clusters which display the rare cubic Fe₈ topology have been obtained by reaction of the metastable hexavacant polyoxotungstate [H₂P₂W₁₂O₄₈]¹²⁻ with basic trinuclear metal acetates.

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Article information

DOI: https://doi.org/10.1039/B510434C
Article type: Communication
Submitted: 22 Jul 2005
Accepted: 29 Sep 2005
First published: 19 Oct 2005

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Chem. Commun., 2005, 5624-5626

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Coordination chemistry of the hexavacant tungstophosphate [H₂P₂W₁₂O₄₈]¹²⁻: synthesis and characterization of iron(III) complexes derived from the unprecedented {P₂W₁₄O₅₄} fragment

B. Godin, J. Vaissermann, P. Herson, L. Ruhlmann, M. Verdaguer and P. Gouzerh, Chem. Commun., 2005, 5624 DOI: 10.1039/B510434C

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Chemical Communications