Issue 33, 2006
From the journal:

Chemical Communications

Functionalization of polyoxometalates by carboxylato and azidoligands: macromolecular complexes and extended compounds

Pierre Mialane,*a   Anne Dolbecqa  and  Francis Sécheressea  

* Corresponding authors

a Institut Lavoisier, UMR 8180, Université de Versailles Saint-Quentin, 45 Avenue des Etats-Unis, France
E-mail: mialane@chimie.uvsq.fr

Abstract

Polyoxometalate compounds continue to be widely studied due to their relevance in various fields such as catalysis or magnetochemistry. In this article, we will focus on two topics we recently developed, the functionalization of rare earth polyoxometalates by organic ligands, which has led to compounds ranging from magnetic macromolecular complexes to a 3D open-framework system, and the functionalization of first row transition metal substituted polyoxometalates by azido ligands, which has allowed the isolation of complexes exhibiting the largest ferromagnetic exchange couplings observed to date in polyoxometalate chemistry.

Graphical abstract: Functionalization of polyoxometalates by carboxylato and azido ligands: macromolecular complexes and extended compounds

About
Cited by
Related
Download options Please wait...

Article information

DOI
https://doi.org/10.1039/B603594A
Article type
Feature Article
Submitted
13 Mar 2006
Accepted
05 May 2006
First published
24 May 2006

Chem. Commun., 2006, 3477-3485

Permissions

Request permissions

Functionalization of polyoxometalates by carboxylato and azido ligands: macromolecular complexes and extended compounds

P. Mialane, A. Dolbecq and F. Sécheresse, Chem. Commun., 2006, 3477 DOI: 10.1039/B603594A

To request permission to reproduce material from this article, please go to the Copyright Clearance Center request page.

If you are an author contributing to an RSC publication, you do not need to request permission provided correct acknowledgement is given.

If you are the author of this article, you do not need to request permission to reproduce figures and diagrams provided correct acknowledgement is given. If you want to reproduce the whole article in a third-party publication (excluding your thesis/dissertation for which permission is not required) please go to the Copyright Clearance Center request page.

Read more about how to correctly acknowledge RSC content.

Social activity

Spotlight

Advertisements