Issue 46, 2007
From the journal:

Dalton Transactions

Atropisomeric phosphinines: design and synthesis†‡

Christian Müller,*a   Evgeny A. Pidko,a   Daniel Totev,a   Martin Lutz,b   Anthony L. Spek,b   Rutger A. van Santena  and  Dieter Vogta  

* Corresponding authors

a Schuit Institute of Catalysis, Department of Chemical Engineering and Chemistry, Eindhoven University of Technology, 5600 MB Eindhoven, The Netherlands
E-mail: c.mueller@tue.nl
Fax: +31 40 245 5054
Tel: +31 40 247 3040

b Bijvoet Center for Biomolecular Research, Department of Crystal and Structural Chemistry, Utrecht University, 3584 CH Utrecht, The Netherlands

Abstract

The first atropisomeric phosphinine was designed and prepared by introducing substituents into specific positions of the heterocyclic framework; the presence of axial chirality was predicted by means of DFT calculations and experimentally verified by chiral HPLC analysis, derivatization experiments as well as temperature dependent 31P{1H} NMR spectroscopy.

Graphical abstract: Atropisomeric phosphinines: design and synthesis

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Article information

DOI
https://doi.org/10.1039/B715197G
Article type
Communication
Submitted
02 Oct 2007
Accepted
03 Oct 2007
First published
10 Oct 2007

Dalton Trans., 2007, 5372-5375

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Atropisomeric phosphinines: design and synthesis

C. Müller, E. A. Pidko, D. Totev, M. Lutz, A. L. Spek, R. A. van Santen and D. Vogt, Dalton Trans., 2007, 5372 DOI: 10.1039/B715197G

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