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Novel perfluorodiphenylphosphinic acid lanthanide (Er or Er-Yb) complex with high NIR photoluminescence quantum yield

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Abstract

A perfluorodiphenylphosphinic acid lanthanide (Er or Er-Yb) complex is synthesized by a one-pot process from perfluorotriphenylphosphine oxide and lanthanide (Er or Er-Yb) chloride; the photoluminescence quantum efficiency reaches 0.98% for the erbium complex and 3.5% for the erbium-ytterbium complex, about 50 times and 175 times, respectively, higher than the usual erbium organic complexes with the hydrogen-containing ligands.

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Notes and references

  1. G. E. Buono-Core, H. Li and B. Marciniak, Coord. Chem. Rev., 1990, 99, 55.

    Article  CAS  Google Scholar 

  2. L. Winkless, R. H. C. Tan, Y. Zheng, M. Motevalli, P. B. Wyatt and W. P. Gillin, Appl. Phys. Lett., 2006, 89, 111115.

    Article  Google Scholar 

  3. Y. Hasegawa, T. Ohkubo, K. Sogabe, Y. Kawamura, Y. Wada, N. Nakashima and S. Yanagida, Angew. Chem., Int. Ed., 2000, 39, 357.

    Article  CAS  Google Scholar 

  4. R. Van Deun, P. Nockemann, C. Gorller-Walrand and K. Binnemans, Chem. Phys. Lett., 2004, 397, 447.

    Article  Google Scholar 

  5. G. Mancino, A. J. Ferguson, A. Beeby, N. J. Long and T. S. Jones, J. Am. Chem. Soc., 2005, 127, 524.

    Article  CAS  Google Scholar 

  6. P. B. Glover, A. P. Bassett, P. Nockemann, B. M. Kariuki, R. V. Deun and Z. Pikramenou, Chem.-Eur. J., 2007, 13, 6308.

    Article  CAS  Google Scholar 

  7. H. Gotter and A. Michaelis, Ber. Dtsch. Chem. Ges., 1878, 11, 885.

    Article  Google Scholar 

  8. E. B. Stucchi, S. L. Scarpari, M. A. Couto Dos Santos and S. R. A. Leite, J. Alloys Compd., 1998, 89, 275–277.

    Google Scholar 

  9. S. L. Scarpari and E. B. Stucchi, J. Alloys Compd., 2001, 740, 323–324.

    Google Scholar 

  10. C. S. Francisco, E. B. Stucchi and E. M. de Abreu, J. Alloys Compd., 2006, 418, 234.

    Article  CAS  Google Scholar 

  11. M. P. Hehlen, N. J. Cockroft, T. R. Gosnell and A. J. Bruce, Phys. Rev. B, 1997, 56, 9302.

    Article  CAS  Google Scholar 

  12. J. Hu, T. W. Odom and C. M. Lieber, Acc. Chem. Res., 1999, 32, 435.

    Article  CAS  Google Scholar 

  13. X. Peng, L. Manna, W. Yang, J. Wickham, E. Scher, A. Kadavanich and A. P. Alivisatos, Nature, 2000, 404, 59.

    Article  CAS  Google Scholar 

  14. G. R. Patzke, F. K. Krumeich and R. Nesper, Angew. Chem., Int. Ed, 2002, 41, 2446.

    Article  CAS  Google Scholar 

  15. L. Guo, C. M. Liu, R. M. Wang, H. B. Xu, Z. Y. Wu and S. H. Yang, J. Am. Chem. Soc., 2004, 126, 4530.

    Article  CAS  Google Scholar 

  16. G. B. Sun, M. H. Cao, Y. H. Wang, C. W. Hu, L. Ren and K. L. Huang, Chem. Commun., 2005, 1740.

    Google Scholar 

  17. X. F. Li, W. S. Liu, W. H. Wang and X. Y. Guo, Chem. Lett., 2002, 31, 1178.

    Article  Google Scholar 

  18. K. W. Oliver, S. J. Rettig, R. C. Thompson, J. Trotter and S. H. Xia, J. Fluorine Chem., 1997, 83, 47.

    Article  CAS  Google Scholar 

  19. C. M. Mikulski, N. M. Karayannis, M. J. Strocko, L. L. Pytlewski and M. M. Labes, Inorg. Chem., 1970, 9, 2053.

    Article  CAS  Google Scholar 

  20. G. H. Dahl and B. P. Block, Inorg. Chem., 1967, 6, 1439.

    Article  CAS  Google Scholar 

  21. G. A. Hebbink, D. N. Reinhoudt and F. C. J. M. Van Veggel, Eur. J. Org. Chem., 2001, 4101.

    Google Scholar 

  22. L. A. Wall, R. E. Donadio and W. J. Pummer, J. Am Chem. Soc., 1960, 82, 4846.

    Article  CAS  Google Scholar 

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Authors and Affiliations

  1. Key Laboratory of Photochemical Conversion and Optoelectronic Materials, Technical Institute of Physics and Chemistry, Chinese Academy of Sciences, Beijing, 100190, P. R. China

    Limei Song, Jin Hu, Jianshe Wang, Xinhou Liu & Zhen Zhen

  2. The Graduate University of Chinese Academy of Sciences, Beijing, 100049, P. R. China

    Limei Song, Jin Hu & Jianshe Wang

Authors
  1. Limei Song
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  2. Jin Hu
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  3. Jianshe Wang
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  4. Xinhou Liu
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  5. Zhen Zhen
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Corresponding author

Correspondence to Zhen Zhen.

Additional information

Electronic supplementary information (ESI) available: Additional experimental data. See DOI: 10.1039/b804117b

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Song, L., Hu, J., Wang, J. et al. Novel perfluorodiphenylphosphinic acid lanthanide (Er or Er-Yb) complex with high NIR photoluminescence quantum yield. Photochem Photobiol Sci 7, 689–693 (2008). https://doi.org/10.1039/b804117b

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  • DOI: https://doi.org/10.1039/b804117b

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