Issue 2, 2009
From the journal:

CrystEngComm

Proton switching of polarity in metalloamphiphile crystals†‡

Jack M. Harrowfield,a   George A. Koutsantonis,*b   Gareth L. Nealon,b   Brian W. Skeltonb  and  Mark A. Spackmanb  

* Corresponding authors

a Institut de Science et d'Ingénierie Supramoléculaires, Université Louis Pasteur, 8, allée Gaspard Monge, Strasbourg, France
E-mail: harrowfield@isis.u-strasbg.fr
Fax: +33-3-90 24 51 40
Tel: +33-3-90 24 51 29

b Chemistry, M313, School of Biomedical, Biomolecular and Chemical Sciences, University of Western Australia, Crawley, Australia
E-mail: george.koutsantonis@uwa.edu.au
Fax: +61-8-6488 7247
Tel: +61-8-6488 3177

Abstract

The metalloamphiphile [Zn(1-decylammonio-8-methylsarcophagine)](ClO4)3·2H2O crystallises in the non-centrosymmetric space group P1 to give a polar crystal, which can be converted to one with a centrosymmetric lattice (space groupI2/a) through deprotonation.

Graphical abstract: Proton switching of polarity in metalloamphiphile crystals

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Article information

DOI
https://doi.org/10.1039/B817145A
Article type
Communication
Submitted
30 Sep 2008
Accepted
03 Nov 2008
First published
05 Dec 2008

CrystEngComm, 2009,11, 249-253

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Proton switching of polarity in metalloamphiphile crystals

J. M. Harrowfield, G. A. Koutsantonis, G. L. Nealon, B. W. Skelton and M. A. Spackman, CrystEngComm, 2009, 11, 249 DOI: 10.1039/B817145A

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