Issue 6, 2009
From the journal:

Chemical Communications

An exceptionally rapid and selective hydrogenation of 2-cyclohexen-1-one in supercritical carbon dioxide†

Maya Chatterjee,*a   Toshirou Yokoyama,a   Hajime Kawanami,*a   Masahiro Satoa  and  Toshishige Suzukia  

* Corresponding authors

a Research Center for Compact Chemical Process, AIST, Tohoku, 4-2-1 Nigatake, Miyagino-ku, Sendai, Japan
E-mail: c-maya@aist.go.jp, h-kawanami@aist.go.jp
Fax: +81 22 237 5215
Tel: +81 22 237 5211

Abstract

Selective hydrogenation of 2-cyclohexen-1-one over Pt–MCM-41 proceeds at a very high rate and produces cyclohexanone with selectivity of 100% in a batch reactor; a marked increase in the reaction rate (TOF) from 2283 min−1 to 5051 min−1 is observed on increasing the pressure from 7 MPa to 14 MPa at 40 °C.

Graphical abstract: An exceptionally rapid and selective hydrogenation of 2-cyclohexen-1-one in supercritical carbon dioxide

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Article information

DOI
https://doi.org/10.1039/B817295A
Article type
Communication
Submitted
02 Oct 2008
Accepted
12 Nov 2008
First published
17 Dec 2008

Chem. Commun., 2009, 701-703

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An exceptionally rapid and selective hydrogenation of 2-cyclohexen-1-one in supercritical carbon dioxide

M. Chatterjee, T. Yokoyama, H. Kawanami, M. Sato and T. Suzuki, Chem. Commun., 2009, 701 DOI: 10.1039/B817295A

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