Issue 12, 2009
From the journal:

CrystEngComm

A novel 3D Mn(II) coordination polymer involving 4,4′-dipyridylsulfide and 4,4′-dipyridyltrisulfide obtained by in situligand formation from 4,4′-dipyridyldisulfide†

Lu-Fang Ma,a   Li-Ya Wang*a  and  Miao Du*b  

* Corresponding authors

a College of Chemistry and Chemical Engineering, Luoyang Normal University, Luoyang, P. R. China
E-mail: wlya@lynu.edu.cn

b College of Chemistry and Life Science, Tianjin Key Laboratory of Structure and Performance for Functional Molecule, Tianjin Normal University, Tianjin, P. R. China
E-mail: dumiao@public.tpt.tj.cn

Abstract

A new coordination polymer, {[Mn(mip)(dps)](dpts)0.5}2n (1) (mip = 5-methylisophthalate) has been solvothermally synthesized by in situ generation of 4,4′-dipyridylsulfide (dps) and 4,4′-dipyridyltrisulfide (dpts) ligands from a 4,4′-dipyridyldisulfide (dpds) precursor. The coordination framework of 1 shows a new (3,5)-connected 3-D net topology with a Schläfli symbol of (42.65.83)(42.6), in which weak antiferromagnetic interactions are observed between the MnII ions.

Graphical abstract: A novel 3D Mn(II) coordination polymer involving 4,4′-dipyridylsulfide and 4,4′-dipyridyltrisulfide obtained by in situ ligand formation from 4,4′-dipyridyldisulfide

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Article information

DOI
https://doi.org/10.1039/B914827M
Article type
Communication
Submitted
21 Jul 2009
Accepted
30 Jul 2009
First published
21 Aug 2009

CrystEngComm, 2009,11, 2593-2596

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A novel 3D Mn(II) coordination polymer involving 4,4′-dipyridylsulfide and 4,4′-dipyridyltrisulfide obtained by in situ ligand formation from 4,4′-dipyridyldisulfide

L. Ma, L. Wang and M. Du, CrystEngComm, 2009, 11, 2593 DOI: 10.1039/B914827M

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