Issue 28, 2010
From the journal:

Chemical Communications

A polyoxometalate-encapsulated 3D porous metal–organic pseudo-rotaxane framework†

Hai-jun Pang,a   Jun Peng,*a   Chun-jing Zhang,a   Yang-guang Li,a   Peng-peng Zhang,a   Hui-yuan Mab  and  Zhong-min Su*a  

* Corresponding authors

a Key Lab of Polyoxometalate Science of the Ministry of Education Faculty of Chemistry, Northeast Normal University, Changchun 130024, P. R. China
E-mail: jpeng@nenu.edu.cn, zmsu@nenu.edu.cn

b College of Chemical and Environmental Engineering, Harbin University of Science and Technology, Harbin 150080, P. R. China

Abstract

A novel compound, [Cu(bimb)]2(HPW12O40)·3H2O (bimb = 1,4-bis(imidazol-1-ylmethyl)biphenyl) with a polyoxometalate-encapsulated 3D metal–organic pseudo-rotaxane framework that can be described as a 2-fold dianet topology showing well-defined 1D nano-scale tunnels, has been synthesized hydrothermally, and its de-/rehydration behavior has been investigated.

Graphical abstract: A polyoxometalate-encapsulated 3D porous metal–organic pseudo-rotaxane framework

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Article information

DOI
https://doi.org/10.1039/C003048A
Article type
Communication
Submitted
12 Feb 2010
Accepted
25 May 2010
First published
15 Jun 2010

Chem. Commun., 2010,46, 5097-5099

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A polyoxometalate-encapsulated 3D porous metal–organic pseudo-rotaxane framework

H. Pang, J. Peng, C. Zhang, Y. Li, P. Zhang, H. Ma and Z. Su, Chem. Commun., 2010, 46, 5097 DOI: 10.1039/C003048A

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