Issue 11, 2010
From the journal:

CrystEngComm

Structural variation from 1D to 3D: effect of metal centers on the construction of metal–organic coordination polymers with N-(1H-tetrazol-5-yl)benzamide ligand†

Y.-B. Wang,a   D.-S. Liu,ab   T.-H. Pan,a   Q. Liang,a   X.-H. Huang,a   S.-T. Wua  and  C.-C. Huang*a  

* Corresponding authors

a State Key Laboratory Breeding Base of Photocatalysis, College of Chemistry & Chemical Engineering, Fuzhou University, Fuzhou, Fujian, P. R. China
E-mail: cchuang@fzu.edu.cn

b College of Chemistry & Chemical Engineering, Jinggangshan University, Ji'an, Jiangxi, P. R. China

Abstract

A new multifunctional semirigid acylamide ligand comprising a tetrazole ring, N-(1H-tetrazol-5-yl)benzamide (HL), has been synthesized, with which five coordination polymers of different metal ions, namely, CdL2 (1), AgL (2), MnL2 (3), CuL2 (4), PbL2 (5), have been prepared and characterized by elemental analysis, infrared spectroscopy and single-crystal X-ray diffraction. The X-ray diffraction analysis reveals that compound 1 crystallized in a chiral space group and is a 3D non-interpenetrated diamondoid framework with Cd(II) centers in tetrahedral geometry. Compound 2 is a 2D coordination polymer with a 3-connected 4·82-fes topology. Compounds 3 and 4 are isomorphous, and both of them exhibit an interesting 2D 44-sql network while compound 5 shows 1D zigzag chains. Thermal stabilities, photoluminescence and NLO properties have also been studied.

Graphical abstract: Structural variation from 1D to 3D: effect of metal centers on the construction of metal–organic coordination polymers with N-(1H-tetrazol-5-yl)benzamide ligand

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Article information

DOI
https://doi.org/10.1039/C003502E
Article type
Paper
Submitted
23 Feb 2010
Accepted
13 May 2010
First published
26 Jul 2010

CrystEngComm, 2010,12, 3886-3893

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Structural variation from 1D to 3D: effect of metal centers on the construction of metal–organic coordination polymers with N-(1H-tetrazol-5-yl)benzamide ligand

Y.-B. Wang, D.-S. Liu, T.-H. Pan, Q. Liang, X.-H. Huang, S.-T. Wu and C.-C. Huang, CrystEngComm, 2010, 12, 3886 DOI: 10.1039/C003502E

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