Issue 13, 2010
From the journal:

Organic & Biomolecular Chemistry

Asymmetric Michael addition of aldehydes to nitroalkenes using a primary amino acid lithium salt†

Masanori Yoshida,*a   Atsushi Satoa  and  Shoji Haraa  

* Corresponding authors

a Division of Chemical Process Engineering, Graduate School of Engineering, Hokkaido University, 8, Kita 13-jo Nishi, Kita-ku, Sapporo, Japan
E-mail: myoshida@eng.hokudai.ac.jp
Fax: +81 11 706 6557
Tel: +81 11 706 6557

Abstract

Enantioselective Michael addition of aldehydes to nitroalkenes was successfully carried out by asymmetric catalysis with L-phenylalanine lithium salt, giving γ-nitroaldehydes in good yields with high enantioselectivity.

Graphical abstract: Asymmetric Michael addition of aldehydes to nitroalkenes using a primary amino acid lithium salt

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Article information

DOI
https://doi.org/10.1039/C003940C
Article type
Paper
Submitted
09 Mar 2010
Accepted
16 Apr 2010
First published
12 May 2010

Org. Biomol. Chem., 2010,8, 3031-3036

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Asymmetric Michael addition of aldehydes to nitroalkenes using a primary amino acid lithium salt

M. Yoshida, A. Sato and S. Hara, Org. Biomol. Chem., 2010, 8, 3031 DOI: 10.1039/C003940C

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