Issue 12, 2010
From the journal:

CrystEngComm

In situ2,5-pyrazinedicarboxylate and oxalate ligands synthesis leading to a microporous europium–organic framework capable of selective sensing of small molecules†

Deyun Ma,a   Weixia Wang,a   Yingwei Li,*a   Jing Li,*ab   Carole Daiguebonne,c   Guillaume Calvezc  and  Olivier Guillou*c  

* Corresponding authors

a School of Chemistry and Chemical Engineering, South China University of Technology, Guangzhou, China
E-mail: liyw@scut.edu.cn
Fax: +86-20-2223-6337
Tel: +86-20-8711-3656

b Department of Chemistry and Chemical Biology, Rutgers University, Piscataway, NJ, USA
E-mail: jingli@rutgers.edu

c UniVersité Europénne de Bretagne-UMR CNRS-INSA 6226, Sciences Chimiques deRennes, 20 Avenue des buttes de Coësmes, Rennes, France
E-mail: olivier.guillou@insa-rennes.fr

Abstract

A new microporous europium-containing metal–organic framework [Eu2(μ2-pzdc)(μ4-pzdc)(μ2-ox)(H2O)4]·8H2O (1) (H2pzdc = 2,5-pyrazinedicarboxylic acid, H2ox = oxalic acid) has been hydrothermally synthesized via an unprecedented in situ formation of 2,5-pyrazinedicarboxylate (pzdc) and oxalate (ox) ligands. Structure 1 was characterized by both single-crystal and powder X-ray diffraction analysis. It can be described as a 4-connected binodal Moganite network with the Schläfli symbol of (4·64·8)2(42·62·82), which exhibits a reversible and highly selective sensing function with respect to acetone.

Graphical abstract: In situ 2,5-pyrazinedicarboxylate and oxalate ligands synthesis leading to a microporous europium–organic framework capable of selective sensing of small molecules

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Article information

DOI
https://doi.org/10.1039/C0CE00135J
Article type
Paper
Submitted
26 Apr 2010
Accepted
12 Jun 2010
First published
13 Aug 2010

CrystEngComm, 2010,12, 4372-4377

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In situ 2,5-pyrazinedicarboxylate and oxalate ligands synthesis leading to a microporous europium–organic framework capable of selective sensing of small molecules

D. Ma, W. Wang, Y. Li, J. Li, C. Daiguebonne, G. Calvez and O. Guillou, CrystEngComm, 2010, 12, 4372 DOI: 10.1039/C0CE00135J

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