Issue 12, 2010
From the journal:

CrystEngComm

Dehydrated Prussian blues for CO2storage and separation applications†

Radha Kishan Motkuri,a   Praveen K. Thallapally,*a   B. Peter McGraila  and  S. Behrooz Ghorishib  

* Corresponding authors

a Energy and Environment Directorate, Pacific Northwest National Laboratory, Richland, WA, USA
Fax: +509 3765368
Tel: +1 509 371 7183

b The Babcock and Wilcox Company, Barberton, Ohio
E-mail: Praveen.Thallapally@pnl.gov

Abstract

Adsorption isotherms of pure gases present in flue and natural gas including CO2, N2, CH4 and water were studied using Prussian blues of chemical formula M3[Co(CN)6]2 (M = Cu, Ni, Mn). These materials adsorbed 8–12 wt% of CO2 at room temperature and 1 bar of pressure with heats of adsorption ranging from 6 to 16 kcal mol−1.

Graphical abstract: Dehydrated Prussian blues for CO2 storage and separation applications

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Article information

DOI
https://doi.org/10.1039/C0CE00199F
Article type
Communication
Submitted
11 May 2010
Accepted
13 Aug 2010
First published
07 Sep 2010

CrystEngComm, 2010,12, 4003-4006

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Dehydrated Prussian blues for CO2 storage and separation applications

R. K. Motkuri, P. K. Thallapally, B. P. McGrail and S. B. Ghorishi, CrystEngComm, 2010, 12, 4003 DOI: 10.1039/C0CE00199F

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