Issue 5, 2011

Novel PEG functionalized graphenenanosheets: enhancement of dispersibility and thermal stability

Abstract

A series of polyethylene glycol (PEG) functionalized graphene sheet hybrid materials (FGHMs) have been successfully synthesized viaester linkages. Interestingly, our products can be dispersed in both polar/protic solvents and nonpolar/nonprotic ones, which differ significantly from previously reported systems and are of great value in the wide-spread application of these “carbon nanosheet” based materials by solution-phase processing. Furthermore, the addition of PEG-modified carbon nanosheets as nanofillers significantly improves the thermal stability of the bulk polymers. In our case, an increase of 35 K in thermal stability can be obtained for PEG4000 after filling with as low as 1 wt % of the PEG modified carbon sheets, suggesting their great potential as novel nanofillers in industry.

Graphical abstract: Novel PEG functionalized graphene nanosheets: enhancement of dispersibility and thermal stability

Supplementary files

Article information

Article type
Paper
Submitted
30 Nov 2010
Accepted
07 Jan 2011
First published
17 Feb 2011

Nanoscale, 2011,3, 2169-2174

Novel PEG functionalized graphene nanosheets: enhancement of dispersibility and thermal stability

S. Zhang, P. Xiong, X. Yang and X. Wang, Nanoscale, 2011, 3, 2169 DOI: 10.1039/C0NR00923G

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