Issue 18, 2011
From the journal:

Chemical Communications

Side chain Co(i)polymers featuring acrylate functionalized neutral 18 electron CpCo(C4R4) (R = Ph, Me) units†

Preeti Chadhaa  and  Paul J. Ragogna*a  

* Corresponding authors

a The University of Western Ontario, 1151 Richmond St., London, ON, Canada
E-mail: pragogna@uwo.ca
Fax: +1 519-661-3022
Tel: +1 519-661-2111 ext 87048

Abstract

The synthesis of novel Co(I) polymers featuring CpCo(C4R4) units are reported. The cyclopentadienyl ring on the CpCo(C4R4) unit has been functionalized with acrylate or methacrylate groups. Acrylate derivatives of these compounds were found to polymerize giving rise to the first example of polymers containing neutral, 18 e cobaltoarenocenes in the side chain.

Graphical abstract: Side chain Co(i) polymers featuring acrylate functionalized neutral 18 electron CpCo(C4R4) (R = Ph, Me) units

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Article information

DOI
https://doi.org/10.1039/C1CC11076D
Article type
Communication
Submitted
23 Feb 2011
Accepted
17 Mar 2011
First published
31 Mar 2011

Chem. Commun., 2011,47, 5301-5303

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Side chain Co(I) polymers featuring acrylate functionalized neutral 18 electron CpCo(C4R4) (R = Ph, Me) units

P. Chadha and P. J. Ragogna, Chem. Commun., 2011, 47, 5301 DOI: 10.1039/C1CC11076D

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