Issue 21, 1971
From the journal:

Journal of the Chemical Society D: Chemical Communications

Photoelectron spectra of electron-rich olefins and an isostructural boron compound; olefins of exceptionally low first ionisation potential

B. Cetinkaya,   G. H. King,   S. S. Krishnamurthy,   M. F. Lappert  and  J. B. Pedley  

Abstract

The photoelectron (P.E.) spectra of C2(NMe2)4 and {C[N(Me)CH2]2}2 each show five bands below 10·5 eV with the first vertical ionisation potential at 5·95 or 6·06 eV (cf., C2H4, 10·5 eV; Na 5·1 eV), as is consistent with their strong reducing properties; these bands are assigned as π levels of various symmetries on the basis of (i) a good fit for experimental data with a simple Hückel calculation, and (ii) comparison of the spectra of the isostructural molecules C2(NMe2)4 and B2(NMe2)4.

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Article information

DOI
https://doi.org/10.1039/C29710001370
Article type
Paper

J. Chem. Soc. D, 1971, 1370-1371

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Photoelectron spectra of electron-rich olefins and an isostructural boron compound; olefins of exceptionally low first ionisation potential

B. Cetinkaya, G. H. King, S. S. Krishnamurthy, M. F. Lappert and J. B. Pedley, J. Chem. Soc. D, 1971, 1370 DOI: 10.1039/C29710001370

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