Issue 33, 2012
From the journal:

Chemical Communications

High-spin versus spin-crossover versus low-spin: geometry intervention in cooperativity in a 3D polymorphic iron(ii)–tetrazole MOFs system†

Zheng Yan,‡a   Mian Li,‡a   Hui-Ling Gao,a   Xiao-Chun Huang*a  and  Dan Li*a  

* Corresponding authors

a Department of Chemistry, Shantou University, Guangdong 515063, P. R. China
E-mail: xchuang@stu.edu.cn, dli@stu.edu.cn
Fax: +86-0754-82902767
Tel: +86-0754-82902589

Abstract

Reported here are three 3D metal–organic framework (MOF) polymorphs with the chemical formula [Fe2(H0.67bdt)3]·xH2O (H2bdt = 5,5′-(1,4-phenylene)bis(1H-tetrazole)), all of which are constructed from similar FeII–tetrazole rod secondary building units (SBUs) via covalent links, but exhibit diverse spin states regulated by inter-chain cooperativity.

Graphical abstract: High-spin versus spin-crossover versus low-spin: geometry intervention in cooperativity in a 3D polymorphic iron(ii)–tetrazole MOFs system

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Article information

DOI
https://doi.org/10.1039/C2CC18140A
Article type
Communication
Submitted
29 Dec 2011
Accepted
27 Feb 2012
First published
29 Feb 2012

Chem. Commun., 2012,48, 3960-3962

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High-spin versus spin-crossover versus low-spin: geometry intervention in cooperativity in a 3D polymorphic iron(II)–tetrazole MOFs system

Z. Yan, M. Li, H. Gao, X. Huang and D. Li, Chem. Commun., 2012, 48, 3960 DOI: 10.1039/C2CC18140A

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