Issue 15, 2013

Spontaneous resolution of 3D chiral hexadecavanadate-based frameworks incorporating achiral flexible and rigid ligands

Abstract

Introducing of mixed flexible and rigid achiral ligands into the hexadecavanadate skeleton leads to the isolation of two enantiomerically 3D chiral hexadecavanadate derivatives, which represent the first example of chiral polyoxometalate-based framework functionalized with mixed flexible and rigid achiral ligands.

Graphical abstract: Spontaneous resolution of 3D chiral hexadecavanadate-based frameworks incorporating achiral flexible and rigid ligands

Supplementary files

Article information

Article type
Communication
Submitted
19 Oct 2012
Accepted
23 Nov 2012
First published
26 Nov 2012

CrystEngComm, 2013,15, 2783-2785

Spontaneous resolution of 3D chiral hexadecavanadate-based frameworks incorporating achiral flexible and rigid ligands

Y. Teng, B. Dong, J. Peng, S. Zhang, L. Chen, L. Song and J. Ge, CrystEngComm, 2013, 15, 2783 DOI: 10.1039/C2CE26719E

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