SCHEDULED MAINTENANCE
Reaction of trans-[M(N2)2(dppe)2](M = Mo or W, dppe = Ph2PCH2CH2PPh2) with hydrogen halides (HY) yields [MY2(N2H2)(dppe)2] which, when M = W and Y = Cl, gives salts [WCl(N2H2)(dppe)2]Z (Z = BPh4– or ClO4–) with sodium tetraphenylborate or lithium perchlorate; [WH(N2)2(dppe)2][HCl2] may also be obtained by reaction of trans-[W(N2)2(dppe)2] with hydrogen chloride.
J. Chatt, G. A. Heath and R. L. Richards, J. Chem. Soc., Chem. Commun., 1972, 1010 DOI: 10.1039/C39720001010
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