Issue 14, 1974

Oxidation of tertiary phosphine ligands by a sulphonyl azide: formation of a phosphine imine derivative of molybdenum(V)

Abstract

A molybdenum(V) derivative of n-propyldiphenylphosphine imine, [MoCl4(NPPrnPh2)(OPPrnPh2)], is formed by oxidation of the tertiary phosphine ligands of [MoCl4(PPrnPh2)2] by p-tolylsulphonyl azide.

Article information

Article type
Paper

J. Chem. Soc., Chem. Commun., 1974, 527-528

Oxidation of tertiary phosphine ligands by a sulphonyl azide: formation of a phosphine imine derivative of molybdenum(V)

D. Scott and A. G. Wedd, J. Chem. Soc., Chem. Commun., 1974, 527 DOI: 10.1039/C39740000527

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