Issue 5, 1977

Synthesis and reactions of molybdenocene dimers: X-ray crystal structure of the salt [{(η-C5H5)Mo}2(µ-OH)(µ-H){µ-(η5-C5H45-C5H4)}]2PF6·½H2O

Abstract

The compounds [{(η-C5H5)MoH[µ-(η1):η5-C5H4]}2](two isomers), [{(η-C5H5)MoH}2{µ-(η5-C5H45-C5H4)}], [{(η-C5H5)MoH}2(µ-H){µ-(η5-C5H45-C5H4)]PF6, [{(η-C5H5)MoI}2[µ-(η5-C5H45-C5H4)]}] and [{(η-C5H5)Mo}2(µ-OH)(µ-H){µ-(η5-C5H45-C5H4)}]2PF6 are described, and the X-ray crystal structure of the last of these is reported.

Article information

Article type
Paper

J. Chem. Soc., Chem. Commun., 1977, 145-146

Synthesis and reactions of molybdenocene dimers: X-ray crystal structure of the salt [{(η-C5H5)Mo}2(µ-OH)(µ-H){µ-(η5-C5H45-C5H4)}]2PF6·½H2O

N. J. Cooper, M. L. H. Green, C. Couldwell and K. Prout, J. Chem. Soc., Chem. Commun., 1977, 145 DOI: 10.1039/C39770000145

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