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Condensation of acetone with bis-(1,4-diaminobutane)copper(II) perchlorate yields a purple product, [(5SR,10RS)-2,4,4,11,11,13-hexamethyl-1,5,10,14-tetra-azacyclo-octadeca-1,13-diene]copper(II) perchlorate, which has an unusual pseudo-tetrahedral geometry about CuII, as indicated by X-ray analysis.
J. W. L. Martin, J. H. Timmons, A. E. Martell, P. Rudolf, A. Clearfield and C. J. Willis, J. Chem. Soc., Chem. Commun., 1979, 999 DOI: 10.1039/C39790000999
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