Issue 4, 1980
From the journal:

Journal of the Chemical Society, Chemical Communications

Stereochemistry of formation of α-(4–6η)-PdCl complexes from steroidal αβ-unsaturated ketones; X-ray crystal structure of the α-(4–6η) progesterone complex of pentane-2,4-dionatopalladium

David J. Collins,   Bryan M. K. Gatehouse,   W. Roy Jackson,   Garry A. Kakos  and  Ray N. Timms  

Abstract

[6β-2H]- and [6α-2H]-Cholest-4-en-3-one react with palladium(II) chloride in dry tetrahydrofuran to give the α-(4–6η)-PdCl compound with highly stereoselective loss of the 6β-deuteron or proton; the α-stereochemistry-has been firmly established by a full X-ray structural analysis of the α-(4–6η)Pd(acac) derivative of progesterone (Hacac = pentane-2,4-dione).

About
Cited by
Related
Download options Please wait...

Article information

DOI
https://doi.org/10.1039/C39800000138
Article type
Paper

J. Chem. Soc., Chem. Commun., 1980, 138-139

Permissions

Request permissions

Stereochemistry of formation of α-(4–6η)-PdCl complexes from steroidal αβ-unsaturated ketones; X-ray crystal structure of the α-(4–6η) progesterone complex of pentane-2,4-dionatopalladium

D. J. Collins, B. M. K. Gatehouse, W. R. Jackson, G. A. Kakos and R. N. Timms, J. Chem. Soc., Chem. Commun., 1980, 138 DOI: 10.1039/C39800000138

To request permission to reproduce material from this article, please go to the Copyright Clearance Center request page.

If you are an author contributing to an RSC publication, you do not need to request permission provided correct acknowledgement is given.

If you are the author of this article, you do not need to request permission to reproduce figures and diagrams provided correct acknowledgement is given. If you want to reproduce the whole article in a third-party publication (excluding your thesis/dissertation for which permission is not required) please go to the Copyright Clearance Center request page.

Read more about how to correctly acknowledge RSC content.

Spotlight

Advertisements