Fe(CO)5, Fe3(CO)12, and [HFe3(CO)11]– supported on inorganic oxides such as Al2O3, La2O3, MgO, or SiO2, exhibit, after decomposition under CO + H2, a very high selectivity in Fischer–Tropsch syntheses for low molecular weight olefins.
D. Commereuc, Y. Chauvin, F. Hugues, J. M. Basset and D. Olivier, J. Chem. Soc., Chem. Commun., 1980, 154 DOI: 10.1039/C39800000154
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