Issue 5, 1981
From the journal:

Journal of the Chemical Society, Chemical Communications

(C5Me5)2UCl·tetrahydrofuran. Oxidative-addition and related reactions

Richard G. Finke,   Yoshiki Hirose  and  Glen Gaughan  

Abstract

The first examples of organoactinide oxidative-addition of alkyl halides are reported, reactions which proceed at unprecedented rates; the results presented include the stoicheiometries of these reactions, the new complexes (C5Me5)2UX2, (C5Me5)2UX(Y), and (C5Me5)2- UY(R)(X,Y = Br, I), the series of halide exchange equilibria by which these new complexes are formed, determination of the appropriate equilibrium constants to ± 10% independent syntheses for these new complexes, and evidence for a previously unknown type of UIII to UIV redox-halide exchange equilibrium and its equilibrium constant.

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Article information

DOI
https://doi.org/10.1039/C39810000232
Article type
Paper

J. Chem. Soc., Chem. Commun., 1981, 232-234

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(C5Me5)2UCl·tetrahydrofuran. Oxidative-addition and related reactions

R. G. Finke, Y. Hirose and G. Gaughan, J. Chem. Soc., Chem. Commun., 1981, 232 DOI: 10.1039/C39810000232

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