Issue 13, 1981
From the journal:

Journal of the Chemical Society, Chemical Communications

closo-Carbametallaboranes with metal–hydrogen bonds from direct insertion into arachno-carbaboranes: the molecular structures of [2-H-2,2-(Et3P)2-1,6,2-C2CoB7H9] and [2-H-2,2-(Et3P)2-1,6,2-C2RhB7H9], and a most unusual crystallographic coincidence

Geoffrey K. Barker,   Maria P. Garcia,   Michael Green,   F. Gordon A. Stone,   Jean-Marie Bassett  and  Alan J. Welch  

Abstract

The arachno-carbaborane 1,3-C2B7H13 reacts with [Co(PEt3)4] and with [Rh(η-C3H5)(PEt3)2] to afford, respectively, [2-H-2,2-(Et3P)2-1,6,2-C2-CoB7H9] and [2-H-2,2-(Et3P)2-1,6,2-C2RhB7H9]; both structures have been established by X-ray diffraction studies, whilst they crystallise in nearly identical unit cells and the same space group, these species are not isostructural.

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Article information

DOI
https://doi.org/10.1039/C39810000653
Article type
Paper

J. Chem. Soc., Chem. Commun., 1981, 653-655

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closo-Carbametallaboranes with metal–hydrogen bonds from direct insertion into arachno-carbaboranes: the molecular structures of [2-H-2,2-(Et3P)2-1,6,2-C2CoB7H9] and [2-H-2,2-(Et3P)2-1,6,2-C2RhB7H9], and a most unusual crystallographic coincidence

G. K. Barker, M. P. Garcia, M. Green, F. G. A. Stone, J. Bassett and A. J. Welch, J. Chem. Soc., Chem. Commun., 1981, 653 DOI: 10.1039/C39810000653

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