Issue 2, 1982
From the journal:

Journal of the Chemical Society, Chemical Communications

Reaction of CS2 with metal cluster carbonyls of the iron triad: synthesis and X-ray crystal structure of [Fe4(CO)12(C2S4)]

Peter V. Broadhurst,   Brian F. G. Johson,   Jack Lewis  and  Paul R. Raithby  

Abstract

Dodecacarbonyltri-iron, [Fe3(CO)12], reacts with an execess of CS2 in hexane at 80 °C under a CO–Ar atmosphere (1:1, pressure ca. 10 atm) to give a number of products in including, in low yield, [Fe4(CO)12(C2S4)] which, on the basis of a single-crystal X-ray analysis, has been shown to contain two Fe2(CO)6 units bridged by a C2S4 unit which may be regarded as a derivative of ethenetetrathiol.

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Article information

DOI
https://doi.org/10.1039/C39820000140
Article type
Paper

J. Chem. Soc., Chem. Commun., 1982, 140-141

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Reaction of CS2 with metal cluster carbonyls of the iron triad: synthesis and X-ray crystal structure of [Fe4(CO)12(C2S4)]

P. V. Broadhurst, B. F. G. Johson, J. Lewis and P. R. Raithby, J. Chem. Soc., Chem. Commun., 1982, 140 DOI: 10.1039/C39820000140

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