Issue 9, 1982
From the journal:

Journal of the Chemical Society, Chemical Communications

The mechanism of protonation of carbyne complexes; X-ray crystal structure of [HMo(CCH2But){P(OMe)3}2(η-C5H5)][BF4] and [Mo(CF3CO2)(CF3CO2H){P(OMe)3}2(η-C5H5)]

Michael Green,   A. Guy Orpen  and  Ian D. Williams  

Abstract

The carbyne hydride complex [HMo(CCH2But){P(OMe)3}2(η-C5H5)][BF4], structurally identified by X-ray crystallography, is formed on protonation of [Mo(CCH2But){P(OMe)3}2(η-C5H5)]With HBF4, whereas with CF3CO2H loss of the carbyne fragment occurs of give [Mo(OCOCF3)(CF30CO2H){P(OMe)3}2(η-C5H5)], suggesting kinetic, charge-controlled attack by a proton on carbon.

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Article information

DOI
https://doi.org/10.1039/C39820000493
Article type
Paper

J. Chem. Soc., Chem. Commun., 1982, 493-495

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The mechanism of protonation of carbyne complexes; X-ray crystal structure of [HMo(CCH2But){P(OMe)3}2(η-C5H5)][BF4] and [Mo(CF3CO2)(CF3CO2H){P(OMe)3}2(η-C5H5)]

M. Green, A. G. Orpen and I. D. Williams, J. Chem. Soc., Chem. Commun., 1982, 493 DOI: 10.1039/C39820000493

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