Issue 6, 1983
From the journal:

Journal of the Chemical Society, Chemical Communications

Reversible addition of hydrogen and carbon monoxide to a closo- triosmiumplatinum cluster: X-ray crystal structures of [Os3Pt(µ-H)4(CO)10{P(C6H11)3}] and [Os3Pt(µ-H)2(CO)11{P(C6H11)3}]

Louis J. Farrugia,   Michael Green,   David R. Hankey,   A. Guy Orpen  and  F. Gordon A. Stone  

Abstract

Treatment of [Os3Pt(µ-H)2(CO)10{P(C6H11)3}] with either H2 or CO results in 1 : 1 adduct formation affording [Os3Pt(µ-H)4(CO)10{P(C6H11)3}] and [Os3Pt(µ-H)2(CO)11{P(C6H11)3}], respectively, both of which revert to the starting complex under N2 purge; the structure of the adduct have been determined by X-ray crystallography, the tetrahydrido-species adopting a closo-structure and the CO complex a butterfly structure for the metal atom core.

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Article information

DOI
https://doi.org/10.1039/C39830000310
Article type
Paper

J. Chem. Soc., Chem. Commun., 1983, 310-312

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Reversible addition of hydrogen and carbon monoxide to a closo- triosmiumplatinum cluster: X-ray crystal structures of [Os3Pt(µ-H)4(CO)10{P(C6H11)3}] and [Os3Pt(µ-H)2(CO)11{P(C6H11)3}]

L. J. Farrugia, M. Green, D. R. Hankey, A. G. Orpen and F. G. A. Stone, J. Chem. Soc., Chem. Commun., 1983, 310 DOI: 10.1039/C39830000310

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